江西华齐铜多金属矿区含矿硅质岩的地球化学特征及成因探讨     

周延 《火山地质与矿产》2011,(1):57-65

矿产远景地质调查过程中,在江西华齐铜多金属矿区发现含矿硅质岩。测试分析显示,区内硅质岩贫A l2O3、T iO2,Co、C r等元素含量低,贫ΣREE,δ（Eu）为负异常,δ（C e）为弱正异常,HREE相对富集等热水沉积物的特征。在判别硅质岩形成的系列图解上,样品均指示热水沉积作用和大陆边缘环境,这与S iO2/A l2O3、S iO2/（K2O＋N a2O）、S iO2/M gO、M nO/T iO2、K/R b等特征值所指示的结果相一致。本区硅质岩地球化学特征及其对比结果说明该区域构造演化的复杂性。在元古代华南海槽构造演化中在华夏地块边缘发生断裂拉张,形成断陷盆地,并发生了热水喷流沉积成岩成矿作用。本区硅质岩与成矿关系密切,研究硅质岩对于认识区域构造演化及寻找矿化体具有重要意义。  相似文献   

Lower crustal melting via magma underplating: Elemental and Sr–Nd–Pb isotopic constraints from late Mesozoic intermediate–felsic volcanic rocks in the northeastern North China Block     

CHAOWEN LI  FENG GUO  WEIMING FAN 《Island Arc》2011,20(4):477-499

Ar–Ar dating, major and trace element analyses, and Sr–Nd–Pb isotope results of two groups of Lower Cretaceous (erupted at 126 and 119 Ma, respectively) intermediate–felsic lava from the northeastern North China Block (NCB) suggest their derivation from melting of mixtures between the heterogeneous lower crust and underplated basalts. Both groups exhibit high‐K calc‐alkaline to shoshonitic affinities, characterized by light rare earth element (LREE) and large ion lithophile element (LILE) enrichment and variable high field strength element (HFSE, e.g. Nb, Ta and Ti) depletion, and moderately radiogenic Sr and unradiogenic Nd and Pb isotopic compositions. Compared with Group 2, Group 1 rocks have relatively higher K₂O and Al₂O₃/(CaO + K₂O + Na₂O) in molar ratio, higher HFSE concentrations and lower Nb/Ta ratios, and higher Sr–Nd–Pb isotope ratios. Group 1 rocks were derived from a mixture of an enriched mantle‐derived magma and a lower crust that has developed radiogenic Sr and unradiogenic Nd and Pb isotopic compositions, whereas the Group 2 magmas were melts of another mixture between the same mantle‐derived component and another type of lower crust having even lower Sr, Nd, and Pb isotopic ratios. Shift in source region from Group 1 to Group 2 coincided with a change in melting conditions: hydrous melting of both the underplated basalt and the lower crust produced the earlier high‐Nb and low‐Nb/Ta melts with little or no residual Ti‐rich phases; while the younger low‐Nb and high‐Nb/Ta magmas were melted under a water‐deficient system, in which Ti‐rich phases were retained in the source. Generation of the two groups of intermediate–felsic volcanic rocks was genetically linked with the contemporaneous magma underplating event as a result of lithospheric thinning in the eastern NCB.  相似文献   

Characteristics and origin of carbon isotopes of n-alkanes in crude oils from the western Pearl River Mouth Basin,South China sea     

《Marine and Petroleum Geology》2015

The quantitative characterization of carbon isotopes of n-alkanes is commonly carried out in organic geochemical studies. Possible controls on carbon isotopes include source organic matter, maturity, fractionation during oil expulsion and migration, and the mixing of different oils. In this study of the origin of crude oils in the western Pearl River Mouth Basin, the influences of all of these factors have been considered in reaching a conclusion. Carbon isotopes of n-alkanes in the crude oils, and the extracts of the two effective source rocks (the Wenchang and Enping formations) in the basin, exhibit clear differences. The Wenchang source rocks have heavy δ¹³C values that remain almost constant or become slightly heavier with increasing carbon number. The Enping source rocks have light δ¹³C values that become lighter with increasing carbon number. Two groups of oils in this area were identified based on the carbon isotopes of the n-alkanes; groupIoils are similar to extracts of the Wenchang source rocks. However, the groupIIoils are different from both the Wenchang and Enping source rocks and the carbon isotopic profiles of their n-alkanes exhibit a “V” feature with increasing carbon number. The results of artificial thermal maturation experiments indicate that, from the early stage to the peak stage of oil generation (with EasyRo between 0.64% and 1.02%), the δ¹³C values of n-alkanes in the pyrolysis oils become heavier by about 3‰ with increasing thermal maturity, but the shape of the carbon isotopic profiles are not significantly changed. Calculated δ¹³C values of n-alkanes in “mixed” artificial pyrolysis oils indicate that the mixture of oils generated from the same source rocks with different maturities could not change the carbon isotopic profile of the n-alkanes, however, a mixing of the Wenchang and Enping oils could give the “V” feature in the profiles, similar to the groupIIoils in this area. The groupIIoils appear to be mixed Wenchang and Enping oils, the latter being the dominant component in the mixture. We conclude that the source organic matter and the degree of mixing are the main factors controlling the carbon isotopic characteristics of n-alkanes in crude oils in the western Pearl River Mouth Basin.  相似文献   

Zircon U-Pb dating of intermediate-acid intrusive rocks in the middle section of Ningzhen district and their metallogenic implicationsEI北大核心CSCD     

Guan J.Wei F.Sun G.Huang J.Wang L. 《大地构造与成矿学》2015,(2):344-354

The Ningzhen metallogenic district is an important part of the Middle-Lower Yangtze River Valley metallogenic belt. LA-ICP-MS zircon U-Pb dating of the three intermediate-acid intrusions, i.e., Anjishan, Xinqiao, and Shima, in the central part of the Ningzhen district, indicates that those intrusions were emplaced in the Late Early Cretaceous, with ages of 107.0±1.1 Ma-108.0±1.6 Ma, 108.0±1.3 Ma, and 102.5±1.1 Ma, respectively. Combined with the molybdenite Re-Os isotope age (106-108 Ma) of porphyry copper deposit in this regions, the Ningzhen district exists an intensively magmatic-metallogenic-thermal event at 102.5-108.0 Ma. The age of this event is similar with the age of the third period of large scale mineralization in South China, however obviously later than the magmatic activity of other ore field (124-148 Ma) in the Middle-Lower Yangtze River Valley metallogenic belt. It is suggested that the tectonic-magmatic-thermal events in the Ningzhen area is formed under regional lithospheric extension environment, which is also consistent with the tectonic background of the third period of large scale mineralization in South China. The zircon U-Pb ages of the intrusions and the Re-Os ages of molybdenites from the porphyry deposits in the study area demonstrate that the Ningzhen district underwent intensive magmatism and hydrothermal mineralization during the period from 102.5 to 108.0 Ma, which is consistent with the third pulse of large scale mineralization in the South China. ©, 2015, Science Press. All right reserved.  相似文献   

胶北地块变质基底超镁铁岩的矿物岩石地球化学特征   总被引：2，自引：2，他引：0  

孔凡梅  刘云  李旭平  郭敬辉  赵国春 《岩石学报》2015,31(6):1549-1563

胶北地块变质基底的蛇纹岩、蛇纹岩化尖晶石方辉橄榄岩、尖晶石橄榄斜方辉石岩、角闪石岩自形成以后,经历了早期的高角闪岩相和晚期绿片岩相的变质作用,因而记录了三个阶段的矿物组合:早期的Opx1+Ol1+Spl1;中期的Opx2+Ol2+Spl2+Amp2和晚期的Amp3+Srp3+Mag3+Cal组合。超镁铁岩中普遍存在的角闪石,具有粒状变晶结构特征,形成于角闪岩相和绿片岩相的变质作用过程。蛇纹石没有受到应力作用的迹象,显示其形成于晚期非挤压环境的交代变质作用过程。尖晶石橄榄岩中斜方辉石的矿物化学以及尖晶石橄榄岩的高Mg O含量都表现出克拉通橄榄岩的性质。角闪石岩的稀土元素配分图解的(La/Sm)N的比值1.11~1.41,(La/Yb)N的比值0.91~1.61,超镁铁岩多元素图解显示无高场强元素异常,都表明胶北地块变质基底的超镁铁岩形成的构造背景或是裂谷环境。尖晶石矿物的Mg#0.72~0.79、Cr#0.06~0.12表明交代变质成因。方辉橄榄岩橄榄石的Fo值88.42~90.50、超镁铁质岩石全岩主元素的分散性、较大的∑REE含量变化以及Si/Al-(Mg+Fe)/Al和Mg/Ti-Fe/Ti主元素的比值图解所表现出的超镁铁岩与角闪石岩具有成因联系等,都表明胶北变质基底的超镁铁岩可能是具有堆晶成因的一套幔源岩浆系列。高MgO含量(16%~42%)表现出前寒武纪变质基底的橄榄岩地幔性质;高水含量反映出漫长地质历史时期变质作用过程。  相似文献   

新疆东天山红云滩地区构造-热演化探讨:来自Ar-Ar和(U-Th)/He热年代学的约束   总被引：6，自引：3，他引：3  

孙敬博  孙腾飞  陈文  喻顺  尹继元  李超  张彦  刘新宇 《岩石学报》2015,31(12):3732-3742

红云滩岩体位于东天山觉罗塔格西部,对其进行热演化历史研究对于揭示觉罗塔格地区乃至整个东天山地区的构造-热演化历史具有重要意义。本文对红云滩岩体进行黑云母Ar-Ar、锆石(U-Th)/He和磷灰石(U-Th)/He测年,并结合前人的锆石U-Pb测年结果,精细刻画出该岩体自形成以后经历的热演化过程,并据此识别出东天山红云滩地区发生过多期快速抬升冷却事件。黑云母阶段升温Ar-Ar法同位素定年得到的坪年龄为316.9±1.8Ma,单颗粒锆石和磷灰石(U-Th)/He同位素定年得到的平均年龄分别为213.7±9.6Ma和65.5±1.3Ma。热年代学数据及模拟结果表明东天山红云滩地区自晚古生代以来经历了3个快速冷却阶段,分别为:晚石炭世至早二叠世(ca.330~296Ma)、晚三叠世(222~220Ma)、晚白垩世(91~77Ma)。其中,晚石炭世至早二叠世的快速冷却作用是岩体侵位后与围岩热传导冷却及伴随天山造山隆升冷却综合作用的结果,晚三叠世和晚白垩世的两期快速冷却事件分别与羌塘-欧亚板块、Kohistan-Dras岛弧-拉萨地块碰撞的远程效应造成的东天山地区隆升作用有关。新生代以来,红云滩岩体所在的阿奇山-雅满苏地区构造活动相对较弱,未发生较为明显的隆升作用,与天山西段新生代的构造活动有着明显的差异。  相似文献   

鲁西隆起北侧博兴洼陷新生界碎屑重矿物的物源示踪分析     

许承武  李忠  韩登林 《岩石学报》2015,31(9):2737-2744

利用碎屑重矿物对鲁西隆起北侧博兴洼陷的新生界沉积岩开展了碎屑物源示踪分析。通过研究区重矿物聚类分析、源区岩石类型分析并结合薄片和探针分析结果,发现研究区源岩类型多样,既有以绿帘石为代表的亲鲁西变质岩,也有以富含石榴石为代表的亲苏鲁变质岩,同时也有火山岩和沉积岩;从古近纪沙河街组三段沉积期开始源岩中亲苏鲁变质岩不断减少,亲鲁西变质岩和基性火成岩不断增加,至新近纪明化镇组沉积期洼陷内几乎无富含石榴石类型源岩,表明博兴洼陷自古近纪以来一直存在来自鲁西、胶东(超高压带)的物源记录,从古近纪沙河街组三段沉积期开始,胶东的物源供给逐渐减少,而到明化镇组沉积时由于鲁西的快速隆升,胶东与博兴洼陷的物源联系被切断。  相似文献   

甘肃北山红柳沟铜镍矿化基性-超基性岩体SHRIMP锆石U-Pb年龄及其地质意义   总被引：2，自引：1，他引：1       下载免费PDF全文

谢燮 杨建国王小红王 磊江 磊  姜安定 《中国地质》2015,(2):396-405

红柳沟铜镍矿化基性-超基性岩体位于塔里木板块北缘北山裂谷带,岩体两侧分别为大山头—岗流脑子、方山口—庙庙井—双鹰山2条区域性深大断裂带。岩体侵位于敦煌岩群,铜镍矿化通常赋存于杂岩体中二辉橄榄岩、橄榄二辉辉长岩、橄榄苏长辉长岩等基性程度较高的岩石内。通过SHRIMP锆石U-Pb定年,首次获得红柳沟矿化橄榄角闪辉长苏长岩锆石的U-Pb年龄为(396.7±3.8)Ma,表明该含矿杂岩体的侵位及矿化作用均发生于中泥盆世,结合区内已知黑山和怪石山等铜镍含矿岩体年龄,从而揭示出甘肃北山地区在中—晚泥盆世一直处于陆缘裂谷拉张环境。  相似文献   

湖北赤壁二叠纪一三叠纪之交古海洋沉积环境演化          下载免费PDF全文

邓宝柱  余黎雪  王永标  李国山  孟亚飞 《地球科学》2015,40(2):317-326

晚二叠世时,湖北赤壁位于扬子台地与北部硅质岩盆地的过渡地带.特殊的古地理位置,使该地区发育一套独特的地层 沉积序列.沉积微相、古生物化石和草莓状黄铁矿的综合研究表明,晚二叠世长兴期至早三叠世早期,赤壁剖面沉积环境演化 可分为6个阶段:近氧化的深水台缘硅质岩沉积、含氧量正常的台缘缓坡沉积、火山活动加剧而含氧量正常的台缘缓坡沉积、 大灭绝后严重缺氧环境的沉积、大灭绝后贫氧环境下的沉积、大灭绝后氧化环境的沉积.由于赤壁剖面处在远离陆地的台缘缓 坡环境,陆源剥蚀的影响可能比较有限,因此火山作用带来的营养物质可能是引起大灭绝后海洋缺氧的主要原因.   相似文献   

粤东桃子窝锡矿区火山-次火山岩和花岗岩锆石U-Pb年龄、Hf同位素特征及其意义     

刘鹏  程彦博  王小雨  张翔  高凤颖  廖正国 《岩石矿物学杂志》2015,34(5):620-636

桃子窝锡矿位于莲花山断裂带西段,是典型的火山-次火山岩型锡矿。本文以桃子窝锡矿赋矿火山-次火山岩及花岗岩为研究对象,首次开展LA-ICP-MS锆石U-Pb定年和Hf同位素特征研究。获得两个次火山岩样品的锆石206Pb/238 U加权平均年龄为172.1±1.1 Ma和171.8±0.9 Ma,一个花岗岩样品的锆石206 Pb/238 U加权平均年龄为168.9±1.5 Ma,表明桃子窝锡矿火山-侵入岩为中侏罗世同一岩浆事件不同阶段的产物。锆石εHf(t)值大多数为负值,只有3个点的值大于0,变化于-13.96~9.53之间,平均值为-7.92。在εHf(t)-t图解上,εHf(t)值大多落在球粒陨石演化线之下,有3个点落在球粒陨石与亏损地幔演化线之间。二阶段模式年龄除3个点介于609.6~795.5 Ma外,其余点年龄为1 450.8~2 102.5 Ma,Hf同位素特征指示成岩物质主要来源于早中元古代古老地壳的部分熔融,还有新元古代新生地壳物质的加入。结合区内已有的研究成果,认为桃子窝锡矿及有关的火山-次火山岩与中生代太平洋板块向欧亚大陆俯冲有关。  相似文献